Simandl, G.J., Paradis, S. and
Birkett, T. (1999): Schist-hosted Emeralds; in Selected British Columbia Mineral Deposit
Profiles, Volume 3, Industrial Minerals, G.J. Simandl, Z.D. Hora and D.V. Lefebure,
Editors, British Columbia Ministry of Energy and Mines, Open File 1999-10.
IDENTIFICATION
SYNONYMS: Emerald deposits
commonly described as "suture zone-related", "pegmatite-related
schist-hosted" or "exometamorphic", "exometasomatic",
"biotite schist-type", "desilicated pegmatite related" and
"glimerite-hosted" are covered by this model.
COMMODITIES (BYPRODUCTS): Emerald
(industrial grade beryl, other gemstones, such as aquamarine, chrysoberyl, phenakite,
tourmaline).
EXAMPLES (British Columbia - Canadian/International):
Socoto and Carnaiba deposits (Brazil), Habachtal (Austria),
Perwomaisky, Mariinsky, Aulsky, Krupsky, Chitny and Tsheremshansky deposits (Russia),
Franqueira (Spain), Gravelotte mine (South Africa), Mingora Mines (Pakistan).
GEOLOGICAL CHARACTERISTICS
CAPSULE DESCRIPTION: Emerald
deposits principally related to mafic and ultramafic schists or unmetamorphosed ultramafic
rocks in contact with felsic rocks, either pegmatoid dykes, granitic rocks, paragneisses
or orthogneisses. Such contacts may be either intrusive or tectonic.
TECTONIC SETTING: Found
in cratonic areas as well as in mobile belts. In many cases related to major Phanerozoic
or Proterozoic suture zones that may involve island arc-continent or continent-continent
collision zones. The lithological assemblages related to suture zones commonly form a
"tectonic mélange" and in some areas are described as "ophiolitic
melange".
DEPOSITIONAL ENVIRONMENT / GEOLOGICAL SETTING: Mainly
in greenstone belts, but also in other areas where Cr-bearing rocks may be adjacent to
pegmatites, aplites, granites and other felsic rocks rich in beryllium. Metamorphic grade
is variable; however, it typically reaches green schist to amphibolite facies.
AGE OF MINERALIZATION: The
deposits are hosted by Archean age rocks or younger. The age of mineralization is
typically linked to either a period of tectonic activity or a time of pegmatoid
emplacement.
HOST/ASSOCIATED ROCKS: Biotite
schists ("biotites", "phlogopitites" and "glimerites") are a
particularly favourable host. Other favourable hosts are metamorphosed mafic volcanic
rocks, such as epidote-chlorite-actinolite-bearing rock, chlorite and chlorite-talc
schists, talc and talc-carbonate schists, white mica schists, mafic schists and gneisses
and amphibolites. Less commonly emeralds occur in unmetamorphosed mafic or ultramafic
rocks and possibly listwaenites. Pegmatites or quartz veins in the contact zone between
granitic rocks and mafic rocks may in some cases host emeralds. A wide variety of rocks
can be associated with schist-hosted emerald deposits, including granite, syenite,
tonalite, granodiorite, a variety of orthogneisses, marbles, black phyllites, white mica
schists, mylonites, cataclasites and other metasedimentary rocks.
DEPOSIT FORM: Most of
the mineralization is hosted by tabular or lenticular mafic schists or "blackwall
zones". Favourable zones are a few metres to tens of metres wide and follow the
contacts between felsic and mafic/ultramafic lithologies for distances of tens to hundreds
of metres, but economically minable portions are typically much smaller. For example,
minable bodies in the Urals average 1 metre in thickness and 25 to 50 metres in length.
Pegmatoids, where present, may form horizontal to steeply dipping pods, lens-shaped or
tabular bodies or anastomosing dykes which may be zoned.
TEXTURE/STRUCTURE: In
blackwall or schists lepidoblastic texture predominates. The individual, discrete
emerald-bearing mafic layers within the favourable zones may be complexly folded,
especially where the mineralization is not spatially associated with pegmatites. Emeralds
are commonly zoned. They may form porphyroblasts, with sigmoidal orientation of the
inclusion trails; beryl may form the rims separating phenakite form the surrounding
biotite schist; or emerald crystals may be embedded in quartz lenses within the biotite
schist. Chrysoberyl may appear as subhedral porphyroblasts or skeletal intergrowths with
emerald, phenakite or apatite.
Where disseminated beryl crystals also occur within pegmatites, they are short, commonly
fractured, prismatic to tabular with poor terminations; but may be up to 2 metres in
length and 1 metre in cross section. Long, prismatic, unfractured crystals occur mainly in
miarolitic cavities.
ORE MINERALOGY: Emerald and
other beryls (in some cases aquamarine or morganite), ± chrysoberyl and industrial grade
beryl. Spodumene gems (in some cases kunzite) may be found in related pegmatites.
GANGUE MINERALOGY [Principal and subordinate]:
In the schist: biotite and/or phlogopite, talc, actinolite,
plagioclase, serpentine, ± fuchsite, ±
quartz, ± carbonates, ± chlorite, ± muscovite, ± pyrite, epidote, ± phenakite, ± milarite and other
beryllium species, ± molybdenite, ±
apatite, ± garnet, ± magnetite, ± ilmenite, ± chromite, ± tourmaline, ± cassiterite.
In the pegmatoids: feldspars (commonly albite), quartz, micas; ± topaz, ±
phenakite , ± molybdenite, ± Sn and W-bearing
minerals, ± bazzite, ± xenotime,
± allanite, ± monazite, ± phosphates, ± pollucite, ± columbite-tantalite, ± kyanite,
zircon, ± beryllonite, ± milarite
and other beryllium species. Emerald crystals may contain actinolite-tremolite,
apatite, biotite, bityite, chlorite, chromite, columbite-tantalite, feldspar, epidote,
fuchsite, garnet, hematite, phlogopite, pyrrhotite, rutile, talc, titanite and tourmaline
inclusions.
ALTERATION MINERALOGY: Limonitization
and pyritization are reported in the host rocks. Kaolinite, muscovite, chlorite,
margarite, bavenite, phenakite, epidimyte, milarite, bityite, bertrandite, euclase are
reported as alteration products of beryl.
WEATHERING: Weathering
contributes to the economic viability of the deposits by softening the matrix, and
concentrating the beryl crystals in the overlaying soil or regolith.
ORE CONTROLS:
1) The principal control is the juxtaposition of beryllium and
chromium-bearing lithologies along deep suture zones. Emerald crystals are present mainly
within the mafic schists and in some cases so called "blackwall zones" as
described ultramafic-hosted talc deposits (M07). In this settings it may be associated
with limonite zones.
2) This often occurs near the contacts of pegmatoids with mafic schists. Emerald
crystals are present mainly within the mafic schists, although in some cases some of the
mineralization may be hosted by pegmatoids.
3) Another prospective setting is along fracture-controlled glimmerite zones.
4) Mineralization may be concentrated along the planes of regional metamorphic
foliation, especially in cores of the folds where the relatively high permeability favors
chemical exchange and the development of synmetamorphic reaction zones between chromium
and beryllium-bearing lithologies.
5) Serpentinite roof pendants in granites are prospective.
GENETIC MODELS: The
origin of schist-hosted emerald deposits is controversial as is the case with many
deposits hosted by metamorphic rocks. All emerald deposits require special geological
conditions where chromium (± vanadium) and beryllium coexist.
Where pegmatoids or plagioclase-rich lenses occur within ultramafic rocks, the
crystalization of emeralds is commonly explained by interaction of pegmatites or
pneumatolytic-hydrothermal, Be-bearing fluids with Cr-bearing mafic/ultramafic rocks. In
other cases, emeralds in schists form by syn- or post-tectonic regional metamorphic
chemical exchange (metasomatism) between felsic rocks, such as felsic gneisses, garnet
mica schists or pre-metamorphic pegmatoids, with the adjacent Cr-bearing rocks such as
schists, gneisses or serpentinites. Contacts between Cr- and Be-bearing source rocks may
be tectonic, as is the case for "suture zone-related" deposits.
ASSOCIATED DEPOSIT TYPES: Feldspar-quartz
and muscovite pegmatites (O03, O04). Mo and W mineralization may be associated with
emeralds. Some porphyry W deposits (L07) have associated beryl.
Tin-bearing granites are in some cases associated with emeralds. Gold was mined at
Gravelotte Emerald Mines (no information about the gold mineralization is available).
COMMENTS: Recently,
microprobe studies have shown that the green color of some beryls is due to vanadium
rather than chrome. In most cases both Cr and V were detected in the beryl crystal
structure. There are two schools of gemmologists, the first believes that
strictly-speaking the vanadium-rich beryls are not emeralds. The second school believes
that gem quality beryls should be named based on their physical, and more particularly,
color properties. It is possible that pegmatoid-related or suture zone-related emerald
deposits hosted by black shales or other chromium and/or vanadium-bearing rocks will be
discovered. In those cases it will be difficult to decide if these deposits are
schist-hosted or Columbia-type (Q06) emeralds.
EXPLORATION GUIDES
GEOCHEMICAL SIGNATURE: The
presence of beryl in eluvial and alluvial deposits is good pathfinder. The distribution of
beryllium in stream sediments proved to be useful in Norway when coupled with
identification of the individual drainage basins and knowledge of the geological
environment.
GEOPHYSICAL SIGNATURE: A
portable field detector that uses 124Sb as a gamma radiation source, the
berylometer, is used to detect Be in outcrop. The instrument should be held less than 4 cm
from the sample. Radiometric surveys may be useful in detecting associated radioactive
minerals where pegmatites are involved. Magnetic and electromagnetic surveys may be useful
in tracing suture zones where ultramafic rocks and felsic rocks are faulted against each
other.
OTHER EXPLORATION GUIDES: Any
Be occurrences in a favorable geological setting should be considered as positive
indicators. If green, chromium and/or vanadium-bearing beryls are the main subject of the
search then ultramafic rocks, black shales or their metamorphic equivalents represent the
most favorable host rocks. If exploration is focused on a variety of gem-quality beryls
(not restricted to emerald), or if the targeted area is not mapped in detail, then Be
occurrences without known spatial association with Cr- or V-bearing lithologies should be
carefully considered. Minerals associated with emeralds in the ores may be considered as
indirect indicators. A wide variety of field-tests based on fluorescence, alkalinity,
staining, density and refractive index have been used in the past to distinguish beryl.
ECONOMIC FACTORS
TYPICAL GRADE AND TONNAGE: The
grade and tonnage of these deposits is difficult to estimate due to erratic emerald
contents (gram/tonne), episodic nature of the mining activity which often results in high
grading, and variability in the quality of gemstones (value/carat). For example, at the
Mingora mines in Islamia Trench two, 15 to 30 centimetres thick layers of talc-rich rock
surrounding quartz lenses contained 1000 to 5000 carats of good stones up to 30 carats in
size. Some of the individual pits in the area produced less than 1000 carats. The
cumulative production of the Mingora emerald mines was reported between 20 000 to over 50
000 carats/year between 1979 and 1988. At Gravelotte Emerald Mine, at least 23 000 kg of
emeralds of varying grades have been produced since 1929 from several zones. For the same
mine promotional literature states that " conservative estimates" of ore within
the Cobra pit are 1.69 million tonnes that could result in production of 17 000 kg of
emeralds ( approximately 1gram /tonne). It is estimated that about 30% of the
emeralds could be sold, but only 2-3% of these are believed to be gem quality. In the
Urals the Mariinsky deposit was explored to a average depth of 500 metres by boreholes and
underground workings. To determine emerald content, bulk samples as large as 200 tonnes
are taken systematically at 100 metres interval along the favourable zone. No grade and
tonnage are available.
ECONOMIC LIMITATIONS: Mining
of precious stones in underdeveloped countries and smaller deposits is done using pick and
shovel with limited use of jackhammers and bulldozers. Larger schist-hosted emerald
deposits, may be successfully exploited by a combination of surface and underground
mining. The Mariinsky deposit was mined by open pit to the depth of 100 metres and is
exploited to the depth of 250 metres by underground methods. "Low impact"
explosives, expanding plastics or hydraulic wedging are used to break the ore. The ore is
milled, screened and manually sorted.
END USES: Transparent and
colored beryl varieties, such as emerald, morganite and aquamarine, are highly valued
gemstones. Industrial grade beryls commonly recovered as by-products are a source of Be
oxide, Be metal alloys used in aerospatial and defence applications, Be oxide ceramics,
large diameter berylium-copper drill rods for oil and gas, fusion reactors, electrical and
electronic components. Berylium metal and oxides are strategic substances, and may be
substituted for by steel, titanium and graphite composites in certain applications.
Phosphor bronze may replace beryllium-copper alloys. However, all known substitutes offer
lower performance than Be-based materials.
IMPORTANCE: Schist-hosted
deposits are the most common source of emeralds, although the largest and most valuable
gemstones are most frequently derived from the Colombia-type deposits. Besides
schist-hosted deposits and pegmatites, beryl for industrial applications may be also be
present in fertile granite and syenite complexes that may be parent to pegmatites. A major
portion of the beryl ore used in the U.S.A. as raw material for beryllium metal is
recovered as a byproduct of feldspar and quartz mining from pegmatites.
REFERENCES
Beus, A.A. (1966): Geochemistry of Beryllium and Genetic Types
of Beryllium Deposits; W.H. Freeman, San Francisco, 401 pages.
Brinck, J.W. and Hofmann, A. (1964): The Distribution of
Beryllium in the Oslo Region, Norway - a Geochemical, Stream Sediment Study; Economic
Geology, Volume 59, pages 79-96.
Frantz, G., Gilg, H.A., Grundmann, G. and Morteani, G. (1996):
Metasomatism at a Granitic Pegmatite-Dunite Contact in Galicia: The Franqueira Occurrence
of Chrysoberyl (alexandrite), Emerald, and Phenakite: Discussion; Canadian Mineralogist,
Volume 34, pages 1329-1331.
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Emerald Deposits of Brazil; Mineralium Deposita, Volume 25, pages 57-64.
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Kazmi, A.H., Anwar, J. and Hussain, S. (1989): Emerald Deposits
of Pakistan; in Emeralds of Pakistan, Geology, Gemology and Genesis, A.H. Kazmi and
L.W. Snee, Editors, Van Nostrand Reinhold Co., New York, USA. Pages 39-74.
Kazmi, A.H., Lawrence, R.D., Anwar, J., Snee, L.W. and Hussain, A.S.
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Ural Emerald Mines; Gems and Gemology, Summer issue, pages 106-113.
Martin-Izard, A., Paniagua, A., Moreiras, D., Aceveddo, R.D. and
Marcos-Pasqual, C. (1995): Metasomatism at a Granitic Pegmatite-Dunite Contact in
Galicia: The Franqueira Occurrence of Chrysoberyl (alexandrite), Emerald and Phenakite; Canadian
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Survey of Canada; Economic Geology Report, Number 23, 109 pages.
Robb, L.J. and Robb, V.M. (1986): Archean Pegmatite Deposits in
the North-eastern Transvaal; in Mineral deposits of South Africa, C.R. Anhaeusser,
and S. Maske, Editors, Geological Society of South Africa, Johannesburg,
Volumes 1 and 2, pages 437-449.
Sinkankas, J. (1959): Gemstones of North America; D. Van
Nostrand Company, Inc., Princeton, 75 pages.
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Company, Radnor, Pennsylvania, pages 1-665.
April 22, 1999
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